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Pentadiynylidyne and Pentacarbido Complexes

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dc.contributor.authorHill, Anthony
dc.contributor.authorManzano, Richard
dc.date.accessioned2020-05-05T00:07:20Z
dc.date.issued2019
dc.date.updated2019-11-25T08:03:35Z
dc.description.abstractThe reaction of the halocarbyne [W(≡CBr)(CO)2(Tp*)] (Tp*=hydrotris(3,5‐dimethylpyrazol‐1‐yl)borate) with trimethylsilyl‐butadiyne, mediated by [Pd(PPh3)4] and CuI, affords the first pentadiynylidyne complex [W(≡CC≡CC≡CSiMe3)(CO)2(Tp*)]. Desilylation provides a general route to heterobimetallic pentacarbido complexes, including [(Tp*)(CO)2W(μ‐C5)(PPh3)2Ru(η‐C5H5)] and [(Ph3P)2(CO)HIr{(μ‐C5)W(CO)2(Tp*)}2].en_AU
dc.description.sponsorshipWe are grateful to the Australian Research Council (DP170102695 and DP190100723) for funding.en_AU
dc.format.mimetypeapplication/pdfen_AU
dc.identifier.issn1433-7851en_AU
dc.identifier.urihttp://hdl.handle.net/1885/203765
dc.language.isoen_AUen_AU
dc.provenancehttps://v2.sherpa.ac.uk/id/publication/1320..."The Accepted Version can be archived in a Non-Commercial Institutional Repository. 12 months embargo" from SHERPA/RoMEO site (as at 11/12/2020).
dc.publisherWileyen_AU
dc.relationhttp://purl.org/au-research/grants/arc/DP170102695en_AU
dc.relationhttp://purl.org/au-research/grants/arc/DP190100723en_AU
dc.rights© 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheimen_AU
dc.sourceAngewandte Chemie International Editionen_AU
dc.titlePentadiynylidyne and Pentacarbido Complexesen_AU
dc.typeJournal articleen_AU
dcterms.accessRightsOpen Access
local.bibliographicCitation.issue22en_AU
local.bibliographicCitation.lastpage7360en_AU
local.bibliographicCitation.startpage7357en_AU
local.contributor.affiliationHill, Anthony, College of Science, ANUen_AU
local.contributor.affiliationManzano, Richard, College of Science, ANUen_AU
local.contributor.authoruidHill, Anthony, u4030185en_AU
local.contributor.authoruidManzano, Richard, u4848014en_AU
local.description.notesImported from ARIESen_AU
local.identifier.absfor039904 - Organometallic Chemistryen_AU
local.identifier.absfor030207 - Transition Metal Chemistryen_AU
local.identifier.absfor030204 - Main Group Metal Chemistryen_AU
local.identifier.absseo970102 - Expanding Knowledge in the Physical Sciencesen_AU
local.identifier.absseo970103 - Expanding Knowledge in the Chemical Sciencesen_AU
local.identifier.ariespublicationu5786633xPUB835en_AU
local.identifier.citationvolume58en_AU
local.identifier.doi10.1002/anie.201902490en_AU
local.identifier.scopusID2-s2.0-85064847068
local.publisher.urlhttps://www.wiley.com/en-gben_AU
local.type.statusAccepted Versionen_AU

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