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Preparation and reactivity of mononuclear platinum(0) complexes containing a η 2 -coordinated alkynylphosphine.

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Date

2002

Authors

Bennett, Martin
Kwan, Laurence
Rae, A David
Wenger, Eric
Willis, Anthony

Journal Title

Journal ISSN

Volume Title

Publisher

Royal Society of Chemistry

Abstract

Displacement of ethene from [Pt(η2-C2H4)(dcpe)] by Ph2PC≡CMe gives the monomeric η2-alkynylphosphine complex [Pt(η2-Ph2PC≡CMe)(dcpe)] (5). Reaction of 5 with one equivalent of HCl forms, in benzene, the four-coordinate η1-vinyl-platinum(II) comple

Description

Keywords

Keywords: Addition reactions; Benzene; Complexation; Dissociation; Hydrochloric acid; Positive ions; Single crystals; Synthesis (chemical); X ray diffraction analysis; Triple bonds; Platinum compounds

Citation

URI

http://hdl.handle.net/1885/72359

Collections

ANU Research Publications

Source

Dalton Transactions

Type

Journal article

Book Title

Entity type

Access Statement

License Rights

DOI

Restricted until

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