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A golden ring: molecular gold carbido complexes

Date

Authors

Borren, Elliot

Hill, Anthony

Shang, Rong

Sharma, Manab

Willis, Anthony

Publisher

American Chemical Society

Abstract

Stannylcarbynes [M(≡CSnMe3)(CO)2(Tp*)] [M = Mo, W; Tp* = hydrotris(dimethylpyrazol-1-yl)borate], which are readily obtained via the successive treatment of [M(≡CBr)(CO) 2(Tp*)] with nBuLi and ClSnMe3, serve as effective carbyne transmetalation agents

Keywords

Keywords: Carbynes; CBr; Heteronuclear; Tetrameric; Transmetalation; Gold; Tungsten compounds; Gold compounds; barban; boric acid; gold; organometallic compound; palladium; tetramer; tin; article; chemical bond; chemical interaction; chemical structure; complex for

URI

http://hdl.handle.net/1885/63029

Collections

ANU Research Publications

Source

Journal of the American Chemical Society

Type

Journal article

DOI

10.1021/ja400128h

Restricted until

2037-12-31

Downloads

File

Description

01_Borren_A_golden_ring:_molecular_gold_2013.pdf (1.06 MB)

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