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Neighbouring group participation reactions in nitrile- and amido-N-bonded pentaamminecobalt(III) complexes in which the unique ligand contains a remote amide group

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dc.contributor.authorAngus, Patricia
dc.contributor.authorJackson, William Gregory
dc.date.accessioned2015-12-13T22:34:50Z
dc.date.available2015-12-13T22:34:50Z
dc.date.issued2003
dc.date.updated2015-12-11T09:24:23Z
dc.description.abstractThe [(NH3)5CoNCCH2CONH2]3+ ion hydrates in aqueous base to form [(NH3)5CoNHCOCH2CONH2] 2+ (33%) and a cobalt(II) species. The kinetics have been measured: kobsd=((kOH+Kke-)[OH-])/(1+K[OH -]) where K=7.9×103 (pKa=9.9), kOH=50 M-1 s-1 and ke-=1.4×10-2s-1.
dc.identifier.issn0020-1693
dc.identifier.urihttp://hdl.handle.net/1885/76311
dc.publisherElsevier
dc.sourceInorganica Chimica Acta
dc.subjectKeywords: acid; amide; ammonia; base; cobalt complex; dimethyl sulfoxide; imide; ligand; nitrile; water; aqueous solution; article; carbon nuclear magnetic resonance; catalysis; chemical reaction; kinetics; molecular interaction; proton nuclear magnetic resonance; Amides; Intramolecular reaction; Linkage isomers; Rearrangement
dc.titleNeighbouring group participation reactions in nitrile- and amido-N-bonded pentaamminecobalt(III) complexes in which the unique ligand contains a remote amide group
dc.typeJournal article
local.bibliographicCitation.lastpage104
local.bibliographicCitation.startpage95
local.contributor.affiliationAngus, Patricia, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationJackson, William Gregory, University of New South Wales, ADFA
local.contributor.authoruidAngus, Patricia, u9112614
local.description.notesImported from ARIES
local.description.refereedYes
local.identifier.absfor030207 - Transition Metal Chemistry
local.identifier.ariespublicationMigratedxPub5144
local.identifier.citationvolume343
local.identifier.doi10.1016/S0020-1693(02)01215-X
local.identifier.scopusID2-s2.0-0037472460
local.type.statusPublished Version

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