Radical reactivity by computation and experiment

Date

Authors

Coote, Michelle

Publisher

Elsevier

Abstract

This chapter discusses various methods for defining and measuring radical stability, including the familiar radical stabilization energy (RSE), along with some lesser-known alternatives, and explains the difference between stability and persistence. A lar

Keywords

Keywords: Atom transfer radical polymerization; Bond strength; Chain transfer processes; Curve-crossing model; Free-radical copolymerization; Free-radical polymerization; Halogen transfer; Hammett parameters; Hydrogen transfer; Kinetics; Linear free-energy relation

URI

http://hdl.handle.net/1885/62973

Collections

ANU Research Publications

Type

Book Title

Polymer Science: A Comprehensive Reference

DOI

10.1016/B978-0-444-53349-4.00062-5

Restricted until

2037-12-31

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01_Coote_Radical_reactivity_by_2012.pdf (403.24 KB)

02_Coote_Radical_reactivity_by_2012.pdf (3.07 MB)