Cultural advice

The Australian National University acknowledges, celebrates and pays our respects to the Ngunnawal and Ngambri people of the Canberra region and to all First Nations Australians on whose traditional lands we meet and work, and whose cultures are among the oldest continuing cultures in human history.

Aboriginal and Torres Strait Islander peoples are advised that ANU Library collections may include images, names, voices, and other representations of deceased persons.

Material in the collection may contain terms, language or views that reflect the period in which the item was created and may be considered inappropriate today.

Radical Ring-Opening Polymerization of Phosphorus Heterocylces: Computational Design of Suitable Phosphetane Monomers

Thumbnail Image

Date

2007

Authors

Coote, Michelle
Hodgson, Jennifer
Krenske, Elizabeth
Namazian, Mansoor
Wild, Stanley (Bruce)

Journal Title

Journal ISSN

Volume Title

Publisher

CSIRO Publishing

Abstract

High-level ab initio calculations have been used to determine the propensities of various phosphetanes towards radical ring-opening polymerization. At the G3(MP2)-RAD level of theory, the propagation rate constants of 1-methylphosphetane (7.5 × 104 L mol

Description

Keywords

Keywords: Copolymerization; Enantioselectivity; Free radical polymerization; Microstructure; Rate constants; Ring opening polymerization; Substitution reactions; Phosphetanes; Propagation rate; t-butyl substituent; Phosphorus

Citation

URI

http://hdl.handle.net/1885/49738

Collections

ANU Research Publications

Source

Australian Journal of Chemistry

Type

Journal article

Book Title

Entity type

Access Statement

License Rights

DOI

10.1071/CH07121

Restricted until

2037-12-31

Downloads

File
Description
01_Coote_Radical_Ring-Opening_2007.pdf (453.96 KB)

DSpace software copyright © 2002-2026 LYRASIS