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Stoichiometric Regio- and Stereoselective Oxidative Coupling Reactions of Conjugated Dienes with Ruthenium(0). A Mechanistic Insight into the Origin of Selectivity

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Date

2011

Authors

Hirano, Masafumi
Sakate, Yumiko
Komine, Nobuyuki
Komiya, Sanshiro
Wang, Xian-qi
Bennett, Martin

Journal Title

Journal ISSN

Volume Title

Publisher

American Chemical Society

Abstract

Treatment of [Ru(η6-C10H8) (η4-1,5-COD)] (1) with excess butadiene at room temperature produces supine,prone-[Ru(η3:η3-2,6-octadiene-1,8- diyl)( η4-1,5-COD)] (supine,prone-2). Similar treatment of 1 with isoprene and (E)-and (Z)-1,3-pentadiene also g

Description

Keywords

Keywords: Conjugated dienes; Low temperatures; NMR studies; Octadiene; Oxidative coupling reactions; Oxidative couplings; Pentadiene; Room temperature; Stereo-selective; Olefins; Ruthenium; Stereochemistry; Butadiene

Citation

URI

http://hdl.handle.net/1885/58243

Collections

ANU Research Publications

Source

Journal of the American Chemical Society

Type

Journal article

Book Title

Entity type

Access Statement

License Rights

DOI

10.1021/om100956f

Restricted until

2037-12-31

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Description
01_Hirano_Stoichiometric_Regio-_and_2011.pdf (1.17 MB)

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