Cultural advice

The Australian National University acknowledges, celebrates and pays our respects to the Ngunnawal and Ngambri people of the Canberra region and to all First Nations Australians on whose traditional lands we meet and work, and whose cultures are among the oldest continuing cultures in human history.

Aboriginal and Torres Strait Islander peoples are advised that ANU Library collections may include images, names, voices, and other representations of deceased persons.

Material in the collection may contain terms, language or views that reflect the period in which the item was created and may be considered inappropriate today.

Expect the unexpected. Isolation and characterisation of some unusual organometallic gold(I) complexes

Date

Authors

Bhargava, Suresh Kumar

Mohr, Fabian

Willis, Anthony

Publisher

Elsevier

Abstract

The reaction of equimolar amounts of 2-Li-3-MeC6H3PPh2 and [AuBr(AsPh3)] gives a mixture of the cyclometallated digold(I) complex [Au2(μ-6-MeC6H3-2-PPh2) 2] and the 'half-cyclometallated' complex [(Ph3As)Au(μ-6-MeC6H3-2-PPh 2)AuBr] (1). This complex rep

Keywords

Keywords: carbon; gold; gold complex; mercuric chloride; organometallic compound; article; chemical analysis; chemical bond; chemical procedures; chemical reaction; chemical structure; electrochemical analysis; isolation procedure; oxidation; reaction analysis; str Binuclear; Cyclometallated; Gold; Heteronuclear

URI

http://hdl.handle.net/1885/87686

Collections

ANU Research Publications

Source

Inorganica Chimica Acta

Type

Journal article

DOI

10.1016/S0020-1693(03)00128-2

abcd