Effect of lone-pair stereoactivity on polyhedral volume and structural flexibility: Application to TeIVO6 octahedra
Date
2013
Authors
Christy, Andrew
Mills, S J
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Munksgaard International Publishers
Abstract
The Distortion Theorem implies that the irregularity of bond distances in a distorted coordination polyhedron causes an increase of mean bond distance. Examination of 40 polyhedra containing the lone-pair cation TeIV shows that this does not imply an incr
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Keywords
Keywords: Coordination polyhedra; Distortion theorems; Distortion theory; Lone-pair activities; Polarizable cations; Sphere surfaces; Stereoactivity; Structural flexibilities; Oxygen; Positive ions; Spheres; Geometry distortion theory; lone-pair stereoactivity; polyhedral distortion
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Acta Crystallographica Section B: Structural Science
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Journal article
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Open Access
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