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Gold and Brønsted Acid Catalyzed Hydride Shift onto Allenes: Divergence in Product Selectivity

Date

Authors

Bolte, Benoit

Gagosz, Fabien

Publisher

American Chemical Society

Abstract

A series of allenyl ethers can be transformed into various fused or spiro tetrahydrofurans and tetrahydropyrans following a hydride shift/cyclization sequence. A divergence in product selectivity, which depends on the nature of the catalyst used (Au(I) complex or Brønsted acid), was observed.

Keywords

Keywords: Allenes; Allenyl ethers; Product selectivities; Tetrahydrofurans; Ethers; Gold compounds; Catalyst selectivity; allene derivative; Bronsted acid; deuterium; gold; gold complex; article; biotransformation; catalysis; catalyst; chemical analysis; chemical b

URI

http://hdl.handle.net/1885/63347

Collections

ANU Research Publications

Source

Journal of the American Chemical Society

Type

Journal article

DOI

10.1021/ja202336p

Restricted until

2037-12-31

Downloads

File

Description

01_Bolte_Gold_and_Brønsted_Acid_2011.pdf (2.58 MB)

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