Dispersion of refractive properties of solvents: Chloroform, toluene, benzene, and carbon disulfide in ultraviolet, visible, and near-infrared

Abstract

Refractive indexdispersion formulas have been derived for chloroform, toluene, benzene, and carbon disulfide from a broad range of the experimental refractive index data at 20 °C. The data were examined with the linear least-squares method. The dispersion equations allow one to calculate the values of refractive index required for analysis of nonlinear optical measurements in the UV, visible, and near-IR wavelength range (0.3–2.5 μm) in these liquids and solutions. The indices were compared to those estimated from quantum chemical calculations. A survey of the experimental data revealed that the measurement results published recently [Opt. Mater. 20, 81 (2002); Rev. Sci. Instrum. 65, 2056 (1994); 66, 38 (1995); 69, 1243 (1998)] were significantly different from other data reported in the literature. Show more