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A less carbocentric view of agostic interactions: the complexes [Rh( η 4 -cod){H 2 A(mt) 2 }] (A = B, C + ; mt = Methimazolyl).

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dc.contributor.authorCrossley, Ian R
dc.contributor.authorHill, Anthony
dc.contributor.authorHumphrey, Elizabeth
dc.contributor.authorSmith, Matthew
dc.date.accessioned2015-12-13T22:56:53Z
dc.date.issued2006
dc.date.updated2015-12-11T11:17:36Z
dc.description.abstractThe reaction of [Rh2(μ-Cl)2(cod)2] (cod = 1,5-cyclooctadiene) with Na[H2B(mt)2] (mt = methimazolyl) provides the complex [Rh(cod){H2B(mt)2}] (1), which in turn reacts with CO or CNC6H3Me 2-2,6 to provide the derivatives [RhL2{H 2B(mt)2}] (L = CO (2), CNC
dc.identifier.issn0276-7333
dc.identifier.urihttp://hdl.handle.net/1885/82991
dc.publisherAmerican Chemical Society
dc.sourceOrganometallics
dc.subjectKeywords: Crystal structure; Infrared spectroscopy; Nuclear magnetic resonance spectroscopy; Positive ions; Reaction kinetics; Agostic interactions; C-H-metal interactions; Isoelectronic pair; Organometallics
dc.titleA less carbocentric view of agostic interactions: the complexes [Rh( η 4 -cod){H 2 A(mt) 2 }] (A = B, C + ; mt = Methimazolyl).
dc.typeJournal article
local.bibliographicCitation.issue9
local.bibliographicCitation.lastpage2247
local.bibliographicCitation.startpage2242
local.contributor.affiliationCrossley, Ian R, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationHill, Anthony, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationHumphrey, Elizabeth, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationSmith, Matthew, College of Physical and Mathematical Sciences, ANU
local.contributor.authoruidCrossley, Ian R, u4120782
local.contributor.authoruidHill, Anthony, u4030185
local.contributor.authoruidHumphrey, Elizabeth, u4036986
local.contributor.authoruidSmith, Matthew, u4056077
local.description.embargo2037-12-31
local.description.notesImported from ARIES
local.description.refereedYes
local.identifier.absfor039904 - Organometallic Chemistry
local.identifier.ariespublicationMigratedxPub11186
local.identifier.citationvolume25
local.identifier.doi10.1021/om050942i
local.identifier.scopusID2-s2.0-33646424645
local.type.statusPublished Version

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