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Synthesis and confirmation of structure for the giberellin GA 131 (18-hydroxy-GA 4 )

Date

Authors

Crow, James

Thomson, Regan

Mander, Lewis

Publisher

Royal Society of Chemistry

Abstract

A general method for the hydroxylation of the 18-methyl group in gibberellins has been developed, as demonstrated by the successful synthesis of 18-hydroxy GA4 (GA131) by means of a tandem process involving the conjugate addition of alkoxides to the α-me

Keywords

Keywords: Hydroxylation; Synthesis (chemical); Gibberellins; Intramolecular aldol reaction; Methylene lactone; Organic acids; gibberellin; article; chemical structure; chemistry; electrospray mass spectrometry; nuclear magnetic resonance spectroscopy; synthesis; Gi

URI

http://hdl.handle.net/1885/84936

Collections

ANU Research Publications

Source

Organic and Biomolecular Chemistry

Type

Journal article

DOI

10.1039/b603570a

Restricted until

2037-12-31

Downloads

File

Description

01_Crow_Synthesis_and_confirmation_of_2006.pdf (278.65 KB)