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First determination of the rate constant for ring-closure of an azahexenoyl radical: 6-aza-7-ethyl-5-hexenoyl

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Date

2010

Authors

Kyne, Sarah H
Lin, Ching-Yeh
Ryu, Ilhyong
Coote, Michelle
Schiesser, Carl

Journal Title

Journal ISSN

Volume Title

Publisher

Royal Society of Chemistry

Abstract

Competitive kinetic experiments utilising free radical carbonylation chemistry provide a first estimate for the rate constant for 6-endo cyclization of the 6-aza-7-ethyl-5-hexenoyl radical of (4.8 ± 2.4) × 10 6 s-1 at 90° C in benzene, in good agreemen

Description

Keywords

Keywords: benzene; radical; article; calculation; carbonylation; chemical analysis; chemical structure; cyclization; gas chromatography; kinetics; Aza Compounds; Cyclization; Free Radicals; Kinetics; Molecular Conformation

Citation

URI

http://hdl.handle.net/1885/60374

Collections

ANU Research Publications

Source

Chemical Communications

Type

Journal article

Book Title

Entity type

Access Statement

License Rights

DOI

10.1039/c0cc01262a

Restricted until

2037-12-31

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01_Kyne_First_determination_of_the_2010.pdf (968.63 KB)

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