Reactions of [Ru(CO) 2 (PPh 3 ) 3 ] with alkynylphosphonium salts: a phosphinoallene complex

Date

2009

Authors

Ang, Wee
Cordiner, Richard
Hill, Anthony
Perry, Tamara
Wagler, Jorg

Journal Title

Journal ISSN

Volume Title

Publisher

American Chemical Society

Abstract

[Ru(CO)2(PPh3)3] reacts with either HC=CCH2Br or [HC=CCH2SMe2]Br to provide the σ-allenyl complex [Ru(CH=C=CH2)Br(CO)2(PPh 3)2]; however, with [HC=CCH2PPh3]Br, the salt [Ru(γ2-H2C=C=CHPPh3)(CO) 2(PPh3)2]Br is obtained, which may be described as a comple

Description

Keywords

Keywords: Allenyl; Crystallographic data; Spectroscopic data

Citation

Source

Organometallics

Type

Journal article

Book Title

Entity type

Access Statement

License Rights

Restricted until

2037-12-31