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Directed 1,3-dipolar cycloadditions of ylidene piperazine-2,5-diones

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Date

2003

Authors

Chai, Christina
Edwards, Alison
Wilkes, Bronwyn
Woodgate, Ruth

Journal Title

Journal ISSN

Volume Title

Publisher

Elsevier

Abstract

The reactivities and selectivities of 1,3-dipolar cycloaddition reactions of ylidene piperazine-2,5-diones with mesitonitrile oxide are reported. The stereoselectivities of reactions with chiral ylidene piperazine-2,5-diones can be directed by judicious choice of substituents on the N- and/or C-substituents of the piperazinedione ring.

Description

Keywords

Keywords: nitrile; oxide; piperazine derivative; article; carbon nuclear magnetic resonance; chemical reaction; chirality; cycloaddition; priority journal; stereochemistry; X ray diffraction Amino acids and derivatives; Cycloadditions; Nitrile oxides; X-ray crystal structures

Citation

URI

http://hdl.handle.net/1885/87671

Collections

ANU Research Publications

Source

Tetrahedron

Type

Journal article

Book Title

Entity type

Access Statement

License Rights

DOI

10.1016/j.tet.2003.09.040

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