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Organometallic complexes for nonlinear optics. 41: Syntheses and quadratic NLO properties of 4-{4-(4-nitrophenyl)diazophenyl}ethynylphenylethynyl complexes

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dc.contributor.authorFondum, Timothy
dc.contributor.authorGreen, Katy
dc.contributor.authorRandles , Michael
dc.contributor.authorCifuentes, Marie
dc.contributor.authorWillis, Anthony
dc.contributor.authorTeshome, Ayele
dc.contributor.authorAsselberghs, Inge
dc.contributor.authorClays, Koen Jan
dc.contributor.authorHumphrey, Mark
dc.date.accessioned2015-12-10T22:16:23Z
dc.date.issued2008
dc.date.updated2015-12-09T08:23:39Z
dc.description.abstractThe syntheses of [Au(C{triple bond, long}C-4-C6H4C{triple bond, long}C-4-C6H4N{double bond, long}N-4-C6H4NO2)(PPh3)] (3), trans-[Ru(C{triple bond, long}C-4-C6H4-C{triple bond, long}C-4-C6H4N{double bond, long}N-4-C6H4NO2)Cl(dppm)2] (4), [Ru(C{triple bond, long}C-4-C6H4C{triple bond, long}C-4-C6H4N{double bond, long}N-4-C6H4NO2)(dppe)(η-C5Me5)] (5), and [Ni(C{triple bond, long}C-4-C6H4N{double bond, long}N-4-C6H4NO2)(PPh3)(η-C5H5)] (6) are reported, together with a single-crystal X-ray diffraction study of 4. Quadratic nonlinearities for 3-6 and [Ru(C{triple bond, long}C-4-C6H4NO2)(dppe)(η-C5Me5)] (7) have been determined at 1.064 μm and 1.300 μm by the hyper-Rayleigh scattering (HRS) technique, comparison to related complexes revealing that β values increase on introduction of azo group and π-system lengthening.
dc.identifier.issn0022-328X
dc.identifier.urihttp://hdl.handle.net/1885/50915
dc.publisherElsevier
dc.sourceJournal of Organometallic Chemistry
dc.subjectKeywords: Complexation; Crystal structure; Organometallics; Rayleigh scattering; Ruthenium; Hyper-Rayleigh scattering (HRS) technique; Organometallic complexes; Nonlinear optics Alkynyl; Crystal structure; Non-linear optics; Ruthenium
dc.titleOrganometallic complexes for nonlinear optics. 41: Syntheses and quadratic NLO properties of 4-{4-(4-nitrophenyl)diazophenyl}ethynylphenylethynyl complexes
dc.typeJournal article
local.bibliographicCitation.issue8-9
local.bibliographicCitation.lastpage1613
local.bibliographicCitation.startpage1605
local.contributor.affiliationFondum, Timothy, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationGreen, Katy, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationRandles , Michael , College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationCifuentes, Marie, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationWillis, Anthony, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationTeshome, Ayele, University of Leuven
local.contributor.affiliationAsselberghs, Inge, Catholic University of Leuven
local.contributor.affiliationClays, Koen Jan, Catholic University of Leuven
local.contributor.affiliationHumphrey, Mark, College of Physical and Mathematical Sciences, ANU
local.contributor.authoruidFondum, Timothy, u2543686
local.contributor.authoruidGreen, Katy, u3371566
local.contributor.authoruidRandles , Michael , u3956935
local.contributor.authoruidCifuentes, Marie, u9410034
local.contributor.authoruidWillis, Anthony, u8512028
local.contributor.authoruidHumphrey, Mark, u9400918
local.description.embargo2037-12-31
local.description.notesImported from ARIES
local.identifier.absfor039904 - Organometallic Chemistry
local.identifier.ariespublicationu4005981xPUB213
local.identifier.citationvolume693
local.identifier.doi10.1016/j.jorganchem.2007.11.004
local.identifier.scopusID2-s2.0-41549100108
local.identifier.thomsonID000255891400027
local.type.statusPublished Version

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