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Dihapto carbamoyl (carboxamide) complexes of iron(II)

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Date

2004

Authors

Anderson, Stephen
Berridge, Timothy E
Hill, Anthony
Ng, Ying T
White, Andrew G
Williams, David

Journal Title

Journal ISSN

Volume Title

Publisher

American Chemical Society

Abstract

The carbamoyl ferrate Li[Fe{C(=O)NiPr2}(CO)4] reacts in diethyl ether with Br2PPh3, I2PPh3, or I2 followed by triphenylphosphine to provide the complexes [Fe(η2-OCNiPr2)X-(CO)2(PPh3)] [X = I trans to PPh3 (1a); Br (1b) two isomers], each of which feature

Description

Keywords

Keywords: Bond lengths; Carbamoyl ligands; Cryostatic chromatography; Amines; Carbonylation; Chemical bonds; Complexation; Crystal structure; Crystallography; Data acquisition; Ethers; Light absorption; Molecular structure; Nuclear magnetic resonance spectroscopy;

Citation

URI

http://hdl.handle.net/1885/78051

Collections

ANU Research Publications

Source

Organometallics

Type

Journal article

Book Title

Entity type

Access Statement

License Rights

DOI

10.1021/om0306933

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