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Dihydrobis(methimazolyl)borate and methimazolyl complexes of titanium

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dc.contributor.authorHill, Anthony
dc.contributor.authorSmith, Matthew
dc.date.accessioned2015-12-13T22:36:11Z
dc.date.issued2006
dc.date.updated2015-12-11T09:30:27Z
dc.description.abstractThe reaction kinetics of HnB(mt)4-n salts with high oxidation state titanium complexes of Dihydrobys(methimazolyl) borate and methimazolyl complexes of titanium are analyzed. The synthetic hurdles in the chemistry of niobium(v) and tantalum(v) may be overcome by the inclusion of a π-basic imido co-ligand to reduce the electrophillicity of the metal centre, which allow the isolation of complexes. The two H2B(mt)2 ligands adopt different modes of coordination within the same molecule to provide a collar of sulfur π donors. The compound is the binuclear bis(imido) complex, which apparently arises from the degradation of the H 2B(mt)2 pro-ligand salt.
dc.identifier.issn1477-9226
dc.identifier.urihttp://hdl.handle.net/1885/76654
dc.publisherRoyal Society of Chemistry
dc.sourceDalton Transactions
dc.subjectKeywords: Degradation; Molecular structure; Niobium; Oxidation; Reaction kinetics; Salts; Tantalum; Titanium; Binuclear bis(imido) complex; Dihydrobis(methimazolyl)borate; Electrophillicity; Methimazolyl complexes; Complexation
dc.titleDihydrobis(methimazolyl)borate and methimazolyl complexes of titanium
dc.typeJournal article
local.bibliographicCitation.lastpage30
local.bibliographicCitation.startpage28
local.contributor.affiliationHill, Anthony, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationSmith, Matthew, College of Physical and Mathematical Sciences, ANU
local.contributor.authoruidHill, Anthony, u4030185
local.contributor.authoruidSmith, Matthew, u4056077
local.description.embargo2037-12-31
local.description.notesImported from ARIES
local.description.refereedYes
local.identifier.absfor030207 - Transition Metal Chemistry
local.identifier.ariespublicationMigratedxPub5458
local.identifier.citationvolume1
local.identifier.doi10.1039/b513251g
local.identifier.scopusID2-s2.0-33645532293
local.type.statusPublished Version

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