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[μ 8 -η 4 -2,5-Bis(oct-1-ynyl)thiophene]bis[octacarbonylbis(η 5 -methylcyclopentadienyl)- tetrahedro -diiridiumdimolybdenum] dichloromethane hemisolvate

Date

Authors

Lucas, Nigel

Willis, Anthony

Humphrey, Mark

Publisher

Munksgaard International Publishers

Abstract

The title compound, [Mo4Ir4(η5-C 6H7)4(C20H28S)(CO) 16]·-0.5CH2Cl2, is a mixed-metal dicluster compound in which the cluster modules are linked by a bridging 2,5-bis(oct-1-ynyl)thiophene ligand. The cluster units each have butterfly metal core geometrie

Keywords

Keywords: Alkylation; Anisotropy; Crystal atomic structure; Diffusion; Hydrogen bonds; Parameter estimation; Reflection; Single crystals; Bond distances; Clustering; Inversion image; Mixed-metal clusters; Aromatic compounds

URI

http://hdl.handle.net/1885/82440

Collections

ANU Research Publications

Source

Acta Crystallographica Section E: Structure Reports Online

Type

Journal article

DOI

10.1107/S160053680500214X

Restricted until

2037-12-31

Downloads

File

Description

01_Lucas_[μ_8_-η_4_2005.pdf (204.91 KB)

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