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Probing the transition state via photoelectron and photodetachment spectroscopy of H 3 O - .

Date

Authors

Zhang, Dong Hui

Yang, Minghui

Collins, Michael

Lee, Soo-Y

Publisher

National Academy of Sciences (USA)

Abstract

The H3O- anion has stable and metastable structures that resemble configurations in the vicinity of the transition state for the neutral reactions OH + H2 ↔ H2O + H. Photoelectron spectroscopy of this anion probes the neutral reaction dynamics in the cr

Keywords

Keywords: tritium oxide; accuracy; article; calculation; chemical reaction kinetics; chemical structure; dissociation; mathematical analysis; molecular stability; phase transition; photodetachment spectroscopy; priority journal; quantitative diagnosis; quantum chem

URI

http://hdl.handle.net/1885/72313

Collections

ANU Research Publications

Source

PNAS - Proceedings of the National Academy of Sciences of the United States of America

Type

Journal article

DOI

10.1073/pnas.182297599

Restricted until

2037-12-31

Downloads

File

Description

01_Zhang_Probing_the_transition_state_2002.pdf (330.58 KB)