Use of spin traps to measure the addition and fragmentation rate coefficients of small molecule RAFT-adduct radicals
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Chernikova, Elena
Golubev, Vladimir
Filippov, Anatoly
Lin, Ching-Yeh
Coote, Michelle
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Royal Society of Chemistry
Abstract
Spin traps have been used to obtain the first direct experimental determination of the addition (5 × 106 L mol-1 s-1), fragmentation (8 × 10-3 s-1) and self-termination (6.5 × 102 L mol-1 s-1) rate coefficients in RAFT polymerization using the interact
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Polymer Chemistry
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2037-12-31