Diastereoselective osmium-catalyzed vicinal oxyamination of acyclic allylic alcohol derivatives

Masruri, Masruri; Kanizaj, Nicholas; McLeod, Malcolm

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Diastereoselective osmium-catalyzed vicinal oxyamination of acyclic allylic alcohol derivatives

Date

2014

Authors

Masruri, Masruri

Kanizaj, Nicholas

McLeod, Malcolm

Publisher

John Wiley & Sons Inc.

Abstract

The osmium-catalyzed oxyamination of chiral acyclic allylic alcohol derivatives bearing mono- and 1,1-di-substituted double bonds with benzyl N-(4-tosyloxy)carbamate proceeds with high regioselectivity and moderate levels of diastereoselectivity favoring