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Intramolecular Diels-Alder reactions of ester-linked 1,3,8-nonatrienes

Date

Authors

Cayzer, Tory

Paddon-Row, Michael

Moran, Damian

Payne, Alan

Turner, Peter

Sherburn, Michael

Publisher

American Chemical Society

Abstract

Penta-1,3-dienyl acrylates undergo kinetically controlled intramolecular Diels-Alder (IMDA) reactions and DFT calculations (B3LYP/6-31+G(d)) predict stereoselectivities that are in very good agreement with the experimental values. The nature of the diene

Keywords

Keywords: Acrylics; Reaction kinetics; Strain; Dienes; Intramolecular Diels-Alder (IMDA) reactions; Stereoselectivity; Steric effects; Esters; 1,3,8 nonatriene derivative; acrylic acid derivative; alkadiene; alkene; ester; penta 1,3 dienyl acrylate derivative; uncl

URI

http://hdl.handle.net/1885/81699

Collections

ANU Research Publications

Source

Journal of Organic Chemistry

Type

Journal article

DOI

10.1021/jo0505829

Restricted until

2037-12-31

Downloads

File

Description

01_Cayzer_Intramolecular_Diels-Alder_2005.pdf (495.77 KB)

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