Intramolecular Diels-Alder reactions of ester-linked 1,3,8-nonatrienes
Date
2005
Authors
Cayzer, Tory
Paddon-Row, Michael
Moran, Damian
Payne, Alan
Turner, Peter
Sherburn, Michael
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Publisher
American Chemical Society
Abstract
Penta-1,3-dienyl acrylates undergo kinetically controlled intramolecular Diels-Alder (IMDA) reactions and DFT calculations (B3LYP/6-31+G(d)) predict stereoselectivities that are in very good agreement with the experimental values. The nature of the diene
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Keywords
Keywords: Acrylics; Reaction kinetics; Strain; Dienes; Intramolecular Diels-Alder (IMDA) reactions; Stereoselectivity; Steric effects; Esters; 1,3,8 nonatriene derivative; acrylic acid derivative; alkadiene; alkene; ester; penta 1,3 dienyl acrylate derivative; uncl
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Source
Journal of Organic Chemistry
Type
Journal article
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2037-12-31
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