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Hofmeister series reversal for lysozyme by change in pH and salt concentration: Insights from electrophoretic mobility measurements

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Salis, Andrea
Cugia, Francesca
Parsons, Drew
Ninham, Barry
Monduzzi, Maura

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Royal Society of Chemistry

Abstract

Hofmeister series reversal can occur with change in pH, or increase in salt concentration. The phenomena are a challenge for any theory of ion specific effects. Recent theoretical work predicts how a complex interplay between ionic sizes, hydration and dispersion forces explains Hofmeister series reversal. Electrophoretic mobility measurements on lysozyme suspensions reported here are consistent with the theory.

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Physical Chemistry Chemical Physics

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Restricted until

2037-12-31