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Simple generation of a dirhodium mu-carbido complex via thiocarbonyl reduction

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dc.contributor.authorBarnett, Harrison
dc.contributor.authorBurt, Liam
dc.contributor.authorHill, Anthony
dc.date.accessioned2020-07-09T23:51:02Z
dc.date.issued2018-06-29
dc.date.updated2020-06-23T00:55:55Z
dc.description.abstractThe reaction of [RhCl(CS)(PPh3)2] with excess catecholborane affords the cumulenic carbido complex [Rh2(μ-C)Cl2(PPh3)4] which undergoes phosphine and halide substitution to afford a range of complexes in which the Rh[double bond, length as m-dash]C[double bond, length as m-dash]Rh spine remains intact. Amongst these, the reactions with K[L] (L = H2B(pz)2, H2B(pzMe2)2, HB(pz)3; pz = pyrazol-1-yl) afford [Rh2(μ-C)(PPh3)2(L)2] whilst with K[HB(pzMe2)3] the unsymmetrical complex [Rh2H(μ-C)(μ-C6H4PPh2-2){HB(pzMe2)3}2] is obtained in which the carbido ligand spans d6-Rh(III) and d8-Rh(I) centres.en_AU
dc.description.sponsorshipWe gratefully acknowledge the Australian Research Council (DP170102695) for fundingen_AU
dc.format.mimetypeapplication/pdfen_AU
dc.identifier.issn1477-9226en_AU
dc.identifier.urihttp://hdl.handle.net/1885/205988
dc.language.isoen_AUen_AU
dc.provenancehttps://v2.sherpa.ac.uk/id/publication/18010..."The Accepted Version can be archived in a Non-Commercial Repository. 12 months embargo" from SHERPA/RoMEO site (as at 11/12/2020).
dc.publisherRoyal Society of Chemistryen_AU
dc.relationhttp://purl.org/au-research/grants/arc/DP170102695en_AU
dc.rights© 2018 The Royal Society of Chemistryen_AU
dc.sourceDalton Transactionsen_AU
dc.titleSimple generation of a dirhodium mu-carbido complex via thiocarbonyl reductionen_AU
dc.typeJournal articleen_AU
dcterms.accessRightsOpen Access
dcterms.dateAccepted2018-06-25
local.bibliographicCitation.lastpage9574en_AU
local.bibliographicCitation.startpage9570en_AU
local.contributor.affiliationBarnett, Harrison, College of Science, ANUen_AU
local.contributor.affiliationBurt, Liam, College of Science, ANUen_AU
local.contributor.affiliationHill, Anthony, College of Science, ANUen_AU
local.contributor.authoruidBarnett, Harrison, u5370150en_AU
local.contributor.authoruidBurt, Liam, u6262594en_AU
local.contributor.authoruidHill, Anthony, u4030185en_AU
local.description.notesImported from ARIESen_AU
local.identifier.absfor030204 - Main Group Metal Chemistryen_AU
local.identifier.absfor039904 - Organometallic Chemistryen_AU
local.identifier.absfor030207 - Transition Metal Chemistryen_AU
local.identifier.absseo970102 - Expanding Knowledge in the Physical Sciencesen_AU
local.identifier.absseo970103 - Expanding Knowledge in the Chemical Sciencesen_AU
local.identifier.ariespublicationu4485658xPUB1745en_AU
local.identifier.citationvolume47en_AU
local.identifier.doi10.1039/c8dt02524jen_AU
local.identifier.thomsonID000444190500001
local.publisher.urlhttps://pubs.rsc.org/en_AU
local.type.statusAccepted Versionen_AU

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