Palladium-Catalyzed Ullmann Cross-Coupling of β‑Iodoenones and β‑Iodoacrylates with o‑Halonitroarenes or o‑Iodobenzonitriles and Reductive Cyclization of the Resulting Products To Give Diverse Heterocyclic Systems
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Khan, Faiyaz
Dlugosch, Michael
Liu, Xin
Khan, Marium
Banwell, Martin
Ward, Jas
Carr, Paul D
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American Chemical Society
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The palladium-catalyzed Ullmann cross-coupling of β-iodoenones and β-iodoacrylates such as 5 (X = I) with ohalonitroarenes and o-iodobenzonitriles including 2 affords products such as compound 7. These can be engaged in a range of reductive cyclization reactions leading to heterocyclic frameworks such as 3,4-benzomorphan derivative 43.
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Organic Letters
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