Heterocyclic arsinocarbynes via tandem transmetallation
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Frogley, Benjamin
Hill, Anthony
Kirk, Ryan
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Royal Society of Chemistry
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Gold(i)-catalysed tandem transmetallation (Sn -> Au -> As) of the stannylcarbyne [W(equivalent to(CSnBu3)-Bu-n)(CO)(2)(Tp*)] (Tp* = hydrotris-(dimethylpyrazolyl)borate) with haloarsines gives direct access to a range of novel arsinocarbyne complexes, LnM equivalent to CAsR2, including unusual heterocyclic phenarsazininyl and arsolyl examples.
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Chemical Communications
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2099-12-31
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