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Heterocyclic arsinocarbynes via tandem transmetallation

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Frogley, Benjamin
Hill, Anthony
Kirk, Ryan

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Royal Society of Chemistry

Abstract

Gold(i)-catalysed tandem transmetallation (Sn -> Au -> As) of the stannylcarbyne [W(equivalent to(CSnBu3)-Bu-n)(CO)(2)(Tp*)] (Tp* = hydrotris-(dimethylpyrazolyl)borate) with haloarsines gives direct access to a range of novel arsinocarbyne complexes, LnM equivalent to CAsR2, including unusual heterocyclic phenarsazininyl and arsolyl examples.

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Chemical Communications

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Restricted until

2099-12-31

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