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Phosphine complexes of an enantiomerically pure, atropisomeric arsenium ion

Date

Authors

Kilah, Nathan

Wild, Stanley (Bruce)

Publisher

American Chemical Society

Abstract

The first enantiomerically pure secondary iodoarsine has been prepared by ring closure of (aR)-[{Li(TMEDA)}2{2,2′-bis(methylene)-1, 1′-binaphthylyl}] with dichlorophenylarsine, followed by disproportionation of the resulting seven-membered (aR)-phenyl

Keywords

Keywords: Absolute configuration; Air-stable; Arsenic atom; Binaphthyl; Complex cation; Diastereomers; Disproportionations; H NMR spectra; Hexafluorophosphates; Methoxymethyl; Methylene groups; NMR spectrum; P-chiral phosphines; Phosphine complex; Phosphine exchang

URI

http://hdl.handle.net/1885/60874

Collections

ANU Research Publications

Source

Organometallics

Type

Journal article

DOI

10.1021/om200853d

Restricted until

2037-12-31

Downloads

File

Description

01_Kilah_Phosphine_complexes_of_an_2012.pdf (591.72 KB)

02_Kilah_Phosphine_complexes_of_an_2012.pdf (482.12 KB)