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Hydrogen from Formic Acid via Its Selective Disproportionation over Nanodomain-Modified Zeolites

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dc.contributor.authorAmos, Ruth
dc.contributor.authorEaston, Christopher
dc.contributor.authorHeinroth, Falk
dc.contributor.authorChan, Bun
dc.contributor.authorWard, Antony J.
dc.contributor.authorZheng, Sisi
dc.contributor.authorHaynes, Brian S.
dc.contributor.authorMasters, Anthony Frederick
dc.contributor.authorMaschmeyer, Thomas
dc.contributor.authorRadom, Leo
dc.date.accessioned2016-06-14T23:21:22Z
dc.date.issued2015
dc.date.updated2016-06-14T09:08:30Z
dc.description.abstractSodium germanate is a nontransition-metal catalyst that is active in the selective dehydrogenation of formic acid. However, bulk sodium germanate has a very low surface area, limiting the availability of the germanate sites for catalysis. The dispersion of germanate in the zeolite ZSM-5 has been investigated both computationally and experimentally as a method for the provision of greater surface area and, therefore, higher activity per germanate site. Nanodomain islets of germanate dispersed in the germanium ZSM-5 zeolite invert selectivity from dehydration (in ZSM-5) to dehydrogenation of formic acid, potentially making Na-Ge-ZSM-5 a cost-effective catalyst for releasing hydrogen from formic acid.
dc.identifier.issn2155-5435
dc.identifier.urihttp://hdl.handle.net/1885/103865
dc.publisherAmerican Chemical Society
dc.sourceACS Catalyisis
dc.titleHydrogen from Formic Acid via Its Selective Disproportionation over Nanodomain-Modified Zeolites
dc.typeJournal article
local.bibliographicCitation.issue7
local.bibliographicCitation.lastpage4362
local.bibliographicCitation.startpage4353
local.contributor.affiliationAmos, Ruth, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationEaston, Christopher, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationHeinroth, Falk, University of Sydney
local.contributor.affiliationChan, Bun, University of Sydney
local.contributor.affiliationWard, Antony J., The University of Sydney
local.contributor.affiliationZheng, Sisi, University of Sydney
local.contributor.affiliationHaynes, Brian S., University of Sydney
local.contributor.affiliationMasters, Anthony Frederick, University of Sydney
local.contributor.affiliationMaschmeyer, Thomas, University of Sydney
local.contributor.affiliationRadom, Leo, University of Sydney
local.contributor.authoruidAmos, Ruth, u4986915
local.contributor.authoruidEaston, Christopher, u9500570
local.description.embargo2037-12-31
local.description.notesImported from ARIES
local.identifier.absfor030501 - Free Radical Chemistry
local.identifier.absseo970103 - Expanding Knowledge in the Chemical Sciences
local.identifier.ariespublicationu4821258xPUB6
local.identifier.citationvolume5
local.identifier.doi10.1021/cs501677b
local.identifier.scopusID2-s2.0-84946135844
local.type.statusPublished Version

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