Chemoenzymatic approaches to the decahydro-as-indacene cores associated with the spinosyn class of insecticide
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Banwell, Martin
Hockless, David
Jarrott, Bevyn
Kelly, Brian
Knill, A
Longmore, Robert
Simpson, Gregory Wayne
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Royal Society of Chemistry
Abstract
The enantiopure dienes 8 and 24, which have been prepared by chemoenzymatic methods, engage in Diels-AIder cycloaddition reactions with maleic and citraconic anhydride to give adducts (e.g. 25-27) embodying the ABC-ring system associated with spinosyns A
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Journal of the Chemical Society, Perkin Transactions 1