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Chemoenzymatic approaches to the decahydro-as-indacene cores associated with the spinosyn class of insecticide

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Date

2000

Authors

Banwell, Martin
Hockless, David
Jarrott, Bevyn
Kelly, Brian
Knill, A
Longmore, Robert
Simpson, Gregory Wayne

Journal Title

Journal ISSN

Volume Title

Publisher

Royal Society of Chemistry

Abstract

The enantiopure dienes 8 and 24, which have been prepared by chemoenzymatic methods, engage in Diels-AIder cycloaddition reactions with maleic and citraconic anhydride to give adducts (e.g. 25-27) embodying the ABC-ring system associated with spinosyns A

Description

Keywords

Keywords: Addition reactions; Carboxylation; Esters; Insecticides; Ketones; Polymerization; Stereochemistry; X ray analysis; Diels-Alder cycloaddition reactions; Steric effects; Aromatic hydrocarbons

Citation

URI

http://hdl.handle.net/1885/90359

Collections

ANU Research Publications

Source

Journal of the Chemical Society, Perkin Transactions 1

Type

Journal article

Book Title

Entity type

Access Statement

License Rights

DOI

10.1039/b006759h

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