Cl 3 V( m -S(CH 3 ) 2 ) 3 VCl 3 2- : A First-Row, Face-Shared Bioctahedral Complex with Multiple Metal-Metal Bonding
Date
2003
Authors
Petrie, Simon
Stranger, Robert
Journal Title
Journal ISSN
Volume Title
Publisher
American Chemical Society
Abstract
Density functional theory calculations have been used to investigate the structure and bonding of the d3d3 bioctahedral complexes X3V(μ-S(CH3)2)3 VX32- (X = F-, Cl-, OH-, SH-, NH2-). According to geometry optimizations using the broken-symmetry approach
Description
Keywords
Keywords: amide; bridged compound; chloride; fluoride; halide; hydroxide; ligand; metal complex; sulfide; thiol group; vanadium derivative; article; atom; chemical bond; chemical composition; covalent bond; density; geometry; ligand binding; metal binding; methodol
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Source
Inorganic Chemistry
Type
Journal article