Organometallic complexes for non-linear optics. 51. Second- and third-order non-linear optical properties of alkynylgold complexes

Barlow, Adam; Babgi, Bandar; Samoc, Marek; Corkery, Timothy; Van Cleuvenbergen, Stijn; Asselberghs, Inge; Clays, Koen Jan; Cifuentes, Marie; Humphrey, Mark

Organometallic complexes for non-linear optics. 51. Second- and third-order non-linear optical properties of alkynylgold complexes

Date

2012

Authors

Barlow, Adam

Babgi, Bandar

Samoc, Marek

Corkery, Timothy

Van Cleuvenbergen, Stijn

Asselberghs, Inge

Clays, Koen Jan

Cifuentes, Marie

Humphrey, Mark

Publisher

CSIRO Publishing

Abstract

The alkynes HC≡CC6H2-2,6-Et2-4- C≡CC6H4-4-NO2 (4) and HC≡CC6H4-4-C≡CC6H2-2,6-Et2-4-C≡CC6H4-4-NO2 (6) and gold alkynyl complexes Au{C≡CC6H2-2,5-(OEt)2-4-C≡CC6H4-4-NO2}(PPh3) (7), Au(C≡CC6H2-2,6-Et2-4-C≡CC6H4-4-NO2)(PPh3) (8), and Au(C≡C