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The Enantiocontrolled Synthesis of a Highly Functionalized Cyclohexenone Related to the A-Ring of the Furanosteroid Viridin

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Date

2009

Authors

Findlay, Alison
Gebert, Antje
Cade, Ian
Banwell, Martin

Journal Title

Journal ISSN

Volume Title

Publisher

CSIRO Publishing

Abstract

A seven-step reaction sequence has been used to convert the enantiomerically pure cis-1,2-dihydrocatechol 10 into the cyclohexenone 17a. A near equivalent sequence involving the same starting material has allowed for the synthesis of the regioisomeric system 17b. Compound 17a is related to the A-ring of ent-viridin (ent-1), the non-natural enantiomer of the furanosteroid viridin (1).

Description

Keywords

Keywords: Functionalized; Reaction sequences; Starting materials

Citation

URI

http://hdl.handle.net/1885/17563

Collections

ANU Research Publications

Source

Australian Journal of Chemistry

Type

Journal article

Book Title

Entity type

Access Statement

License Rights

DOI

10.1071/CH09283

Restricted until

2037-12-31

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01_Findlay_The_Enantiocontrolled_2009.pdf (333.62 KB)

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