Spiroacetal Biosynthesis: (±)-1,7-Dioxaspiro[5.5]undecane in Bactrocera cacuminata and Bactrocera oleae (Olive Fruit Fly)
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Schwartz, Brett
McErlean, Christopher S P
Fletcher, Mary T
Mazomenos, Basilis E
Konstantopoulou, Maria A
Kitching, William
De Voss, James Joseph
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American Chemical Society
Abstract
A biosynthetic scheme rationalizing the formation of (±)-1,7- dioxaspiro[5.5]undecane (5) in the fruit fly species Bactrocera cacuminata and Bactrocera oleae (olive fruit fly) is presented. Incorporation studies with deuterium-labeled keto aldehyde (10),
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Organic Letters
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2037-12-31
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