Allenylphosphonium Complexes of Rhodium and Iridium
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Cade, Ian
Colebatch, Annie
Hill, Anthony
Willis, Anthony
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American Chemical Society
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The propargylic salt [Ph3PCH2C≡CH]PF 6 ([1]PF6) undergoes a facile rearrangement to the allenyl isomer [Ph3PCH=C=CH2]PF6 ([2]PF6) upon coordination to rhodium and iridium. The η2- allenylphosphonium salts [IrX(η2-CH2=C=CHPPh 3)(CO)(PPh3)2]PF6 (X = Cl,
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2037-12-31
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