An exploration of the potential of [4+2] cycloadditions of α-pyrones with indenones for the synthesis of the norditerpenoid tropone, harringtonolide

Mander, Lewis; O'Sullivan, Timothy

An exploration of the potential of [4+2] cycloadditions of α-pyrones with indenones for the synthesis of the norditerpenoid tropone, harringtonolide

Date

2003

Authors

Mander, Lewis

O'Sullivan, Timothy

Publisher

Georg Thieme Verlag

Abstract

The Diels-Alder reactions of 5-methoxyindenones with various α-pyrones provide the basis for a new and more efficient approach to the synthesis of the unusual nor-diterpenoid tropone, harringtonolide.

Keywords

Keywords: 2 pyrone derivative; 5 methoxyindenone; diterpenoid; ether; harringtonolide; indene derivative; indenone; tropone derivative; unclassified drug; article; cycloaddition; Diels Alder reaction; synthesis a-pyrone; Cycloaddition; Ether formation; Indenone; Tropone

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http://hdl.handle.net/1885/88397

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ANU Research Publications

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Synlett

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Journal article

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An exploration of the potential of [4+2] cycloadditions of α-pyrones with indenones for the synthesis of the norditerpenoid tropone, harringtonolide

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