Achieving C-N bond cleavage in dinuclear metal cyanide complexes

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dc.contributor.authorCavigliasso, German
dc.contributor.authorChristian, Gemma
dc.contributor.authorStranger, Robert
dc.contributor.authorYates, Brian F
dc.date.accessioned2015-12-10T22:18:59Z
dc.date.issued2011
dc.date.updated2016-02-24T12:14:21Z
dc.description.abstractCleavage of cyanide is more difficult to achieve compared to dinitrogen and carbon monoxide, even though these species contain triple bonds of greater strength. In this work, we have used computational methods to investigate thermodynamic and mechanistic
dc.identifier.issn1477-9226
dc.identifier.urihttp://hdl.handle.net/1885/51649
dc.publisherRoyal Society of Chemistry
dc.sourceDalton Transactions
dc.subjectKeywords: Back-donation; Bond cleavages; Bond scissions; C-N cleavage; Dinitrogen; Dinuclear; Ligand groups; Mechanistic aspects; Metal centres; Metal cyanide complexes; Metal sites; Molecular fragments; Negative charge; Orbital interaction; Orbitals; Triple bonds;
dc.titleAchieving C-N bond cleavage in dinuclear metal cyanide complexes
dc.typeJournal article
local.bibliographicCitation.issue28
local.bibliographicCitation.lastpage7339
local.bibliographicCitation.startpage7327
local.contributor.affiliationCavigliasso, German, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationChristian, Gemma, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationStranger, Robert, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationYates, Brian F, University of Tasmania
local.contributor.authoruidCavigliasso, German, u4050795
local.contributor.authoruidChristian, Gemma, u4027710
local.contributor.authoruidStranger, Robert, u8708796
local.description.embargo2037-12-31
local.description.notesImported from ARIES
local.identifier.absfor030701 - Quantum Chemistry
local.identifier.absseo970103 - Expanding Knowledge in the Chemical Sciences
local.identifier.ariespublicationu9911292xPUB228
local.identifier.citationvolume40
local.identifier.doi10.1039/c1dt10225g
local.identifier.scopusID2-s2.0-79960277925
local.identifier.thomsonID000292987200008
local.type.statusPublished Version

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