Syntheses of Ir 4 (CO) 6 (η 5 -C 5 Me 4 H) 2 and Ir 7 (μ 3 -CO) 3 (CO) 12 (η 5 -C 5 Me 5 ) from Pentametallic Molybdenum-Iridium Cluster Precursors.

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Fu, Junhong (Nate)
Randles , Michael
Criddle, Alan
Moxey, Graeme
Schwich, Torsten
Stranger, Robert
Cifuentes, Marie
Humphrey, Mark

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Wiley-VCH Verlag GMBH

Abstract

Reaction of Mo<inf>2</inf>Ir<inf>3</inf>(μ-CO)<inf>3</inf>(CO)<inf>6</inf>(η5-C<inf>5</inf>H<inf>5</inf>)<inf>2</inf>(η5-C<inf>5</inf>Me<inf>5</inf>) with Ir(CO)<inf>2</inf>(η5-C<inf>5</inf>Me<inf>4</inf>H) afforded the four-valence-electron-deficient

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European Journal of Inorganic Chemistry

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Open Access

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