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High oxidation state bromocarbyne complexes

Date

2017

Authors

Hill, Anthony
Yuze Kong, Richard

Journal Title

Journal ISSN

Volume Title

Publisher

Royal Society of Chemistry

Abstract

Bromination of the carbyne complexes [W(RCR)Br(CO)2(dcpe)] (R = Ph, SiPh3; dcpe = 1,2-bis(dicyclohexylphosphino)ethane) provides high oxidation state derivatives [W(RCPh)Br3(dcpe)] and [W(RCBr)Br3(dcpe)], the latter via an unprecedented bromodesilylation process.

Description

Keywords

Citation

URI

http://hdl.handle.net/1885/216843

Collections

ANU Research Publications

Source

Chemical Communications

Type

Journal article

Book Title

Entity type

Access Statement

Open Access

License Rights

Creative Commons Attribution-NonCommercial 3.0 Unported Licence

DOI

10.1039/c6cc08946a

Restricted until

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c6cc08946a.pdf (1.79 MB)

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