Cultural advice

The Australian National University acknowledges, celebrates and pays our respects to the Ngunnawal and Ngambri people of the Canberra region and to all First Nations Australians on whose traditional lands we meet and work, and whose cultures are among the oldest continuing cultures in human history.

Aboriginal and Torres Strait Islander peoples are advised that ANU Library collections may include images, names, voices, and other representations of deceased persons.

Material in the collection may contain terms, language or views that reflect the period in which the item was created and may be considered inappropriate today.

Mechanistic insight from activation parameters for the reaction between co-enzyme B 12 and cyanide: further evidence that heterolytic Co�C bond cleavage is solvent-assisted.

Thumbnail Image

Date

2003

Authors

Hamza, Mohamed
Cregan, Andrew
Brasch, Nicola E
van Eldik, Rudi

Journal Title

Journal ISSN

Volume Title

Publisher

Royal Society of Chemistry

Abstract

The potential involvement of the solvent in heterolytic Co-C bond cleavage for vitamin B12 derivatives has been probed by measuring for the first time activation parameters for heterolytic Co-C bond cleavage. If a water molecule is part of the transition

Description

Keywords

Keywords: Chemical bonds; Coenzymes; Composition effects; Cyanides; Derivatives; Electron transitions; Nuclear magnetic resonance spectroscopy; Reaction kinetics; Saturation (materials composition); Solvents; Ultraviolet spectroscopy; Activation parameters; Deoxyad

Citation

URI

http://hdl.handle.net/1885/74253

Collections

ANU Research Publications

Source

Dalton Transactions

Type

Journal article

Book Title

Entity type

Access Statement

License Rights

DOI

Restricted until

DSpace software copyright © 2002-2026 LYRASIS