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Temperature-dependent cooperative coiling of helical conformers of enantiopure oligo(tertiary phosphines)

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dc.contributor.authorSwiegers, Gerhard
dc.contributor.authorWild, Stanley (Bruce)
dc.date.accessioned2015-12-13T22:36:12Z
dc.date.issued2005
dc.date.updated2015-12-11T09:30:31Z
dc.description.abstractThe specific optical rotation of an enantiopure, syndiotactic hexa(tertiary phosphine) displays a marked temperature dependence that is consistent with the cooperative formation of helically coiled conformers in solution.
dc.identifier.issn0004-9425
dc.identifier.urihttp://hdl.handle.net/1885/76661
dc.publisherCSIRO Publishing
dc.sourceAustralian Journal of Chemistry
dc.subjectKeywords: Conformations; Optical rotation; Thermal effects; Conformers; Temperature dependence; Oligomers
dc.titleTemperature-dependent cooperative coiling of helical conformers of enantiopure oligo(tertiary phosphines)
dc.typeJournal article
local.bibliographicCitation.issue12
local.bibliographicCitation.lastpage833
local.bibliographicCitation.startpage831
local.contributor.affiliationSwiegers, Gerhard, CSIRO Molecular and Health Technologies
local.contributor.affiliationWild, Stanley (Bruce), College of Physical and Mathematical Sciences, ANU
local.contributor.authoruidWild, Stanley (Bruce), u7901996
local.description.embargo2037-12-31
local.description.notesImported from ARIES
local.description.refereedYes
local.identifier.absfor030204 - Main Group Metal Chemistry
local.identifier.ariespublicationMigratedxPub5462
local.identifier.citationvolume58
local.identifier.doi10.1071/CH05253
local.identifier.scopusID2-s2.0-29144500359
local.type.statusPublished Version

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