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Syntheses and Nonlinear Optical Properties of Alkynylruthenium Dendrimers

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dc.contributor.authorPowell, Clem
dc.contributor.authorCifuentes, Marie
dc.contributor.authorMorrall, Joseph
dc.contributor.authorSamoc, Marek
dc.contributor.authorHumphrey, Mark
dc.date.accessioned2015-12-07T22:20:58Z
dc.date.issued2006
dc.date.updated2015-12-07T08:52:36Z
dc.description.abstractLow-generation alkynylruthenium dendrimers with arylethynyl branching and spacer units have been synthesized. A "steric control" methodology to rapidly afford the necessary organometallic dendrons has been developed. The dendrimer complexes possess interesting nonlinear optical properties, including very large two-photon absorption cross-sections, the wavelength dependence of which has been examined in one case. They also undergo reversible oxidation in solution, which results in both linear and nonlinear electrochromism.
dc.identifier.isbn9780841239296
dc.identifier.urihttp://hdl.handle.net/1885/19828
dc.publisherAmerican Chemical Society
dc.relation.ispartofMetal-Containing and Metallosupramolecular Polymers and Materials
dc.relation.isversionof1st Edition
dc.titleSyntheses and Nonlinear Optical Properties of Alkynylruthenium Dendrimers
dc.typeBook chapter
local.bibliographicCitation.lastpage272
local.bibliographicCitation.placeofpublicationUSA
local.bibliographicCitation.startpage258
local.contributor.affiliationHumphrey, Mark, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationPowell, Clem, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationCifuentes, Marie, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationMorrall, Joseph, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationSamoc, Marek, College of Physical and Mathematical Sciences, ANU
local.contributor.authoruidHumphrey, Mark, u9400918
local.contributor.authoruidPowell, Clem, u9815628
local.contributor.authoruidCifuentes, Marie, u9410034
local.contributor.authoruidMorrall, Joseph, u3043698
local.contributor.authoruidSamoc, Marek, u9115357
local.description.notesImported from ARIES
local.identifier.absfor039904 - Organometallic Chemistry
local.identifier.ariespublicationu9911292xPUB9
local.identifier.scopusID2-s2.0-36949017982
local.type.statusPublished Version

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