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An enantioselective synthesis of the epoxyquinol (+)-isoepiepoformin

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Date

2010

Authors

White, Lorenzo
Dietinger, Christine
Pinkerton, David
Willis, Anthony
Banwell, Martin

Journal Title

Journal ISSN

Volume Title

Publisher

Wiley-VCH Verlag GMBH

Abstract

The epoxyquinol natural product: (+)-isoepiepoformin (1) has been synthesized for the first time and in an unambiguous fashion by using the scalemic cis-l,2-dihydrocatechol 2 as starting material. The spectroscopic data derived from the synthetic sample of compound 1 match those reported in the literature for the natural product and thereby confirm the structure assigned to the latter.

Description

Keywords

(+)-isoepiepoformin, 2-dihydrocatechol, C-C coupling, Cis-l, Enones, Natural products, Total synthesis

Citation

URI

http://hdl.handle.net/1885/57469

Collections

ANU Research Publications

Source

European Journal of Organic Chemistry

Type

Journal article

Book Title

Entity type

Access Statement

License Rights

DOI

10.1002/ejoc.201000642

Restricted until

2037-12-31

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01_White_An_enantioselective_synthesis_2010.pdf (134.22 KB)

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