Mixed-Metal Cluster Chemistry. 29. Core Expansion and Ligand-Driven Metal Exchange at Group 6-Iridium Clusters
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Usher, Alistair
Lucas, Nigel
Dalton, Gulliver
Randles , Michael
Viau, Lydie
Petrie, Simon
Stranger, Robert
Willis, Anthony
Rae, A David
Humphrey, Mark
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American Chemical Society
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Reactions of the tetrahedral clusters Molr3(μ-CO) 3(CO)8(η-L) (L = C5HMe4, C 5Me5) with the carbonylmetalate anions [Mo(CO) 3(η-L)]- afford the trigonal bipyramidal clusters Mo2lr3(μ3-H)(μ-CO)2(CO) 9(η-L)2 (L = C5HMe4 (3c), 74%; L = C5Me5 (3d), 55%)
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Inorganic Chemistry
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2037-12-31
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