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Mixed-Metal Cluster Chemistry. 29. Core Expansion and Ligand-Driven Metal Exchange at Group 6-Iridium Clusters

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Date

2006

Authors

Usher, Alistair
Lucas, Nigel
Dalton, Gulliver
Randles , Michael
Viau, Lydie
Petrie, Simon
Stranger, Robert
Willis, Anthony
Rae, A David
Humphrey, Mark

Journal Title

Journal ISSN

Volume Title

Publisher

American Chemical Society

Abstract

Reactions of the tetrahedral clusters Molr3(μ-CO) 3(CO)8(η-L) (L = C5HMe4, C 5Me5) with the carbonylmetalate anions [Mo(CO) 3(η-L)]- afford the trigonal bipyramidal clusters Mo2lr3(μ3-H)(μ-CO)2(CO) 9(η-L)2 (L = C5HMe4 (3c), 74%; L = C5Me5 (3d), 55%)

Description

Keywords

Citation

URI

http://hdl.handle.net/1885/17550

Collections

ANU Research Publications

Source

Inorganic Chemistry

Type

Journal article

Book Title

Entity type

Access Statement

License Rights

DOI

10.1021/ic061736l

Restricted until

2037-12-31

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01_Usher_Mixed-Metal_Cluster_Chemistry._2006.pdf (432.7 KB)

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