Cultural advice

The Australian National University acknowledges, celebrates and pays our respects to the Ngunnawal and Ngambri people of the Canberra region and to all First Nations Australians on whose traditional lands we meet and work, and whose cultures are among the oldest continuing cultures in human history.

Aboriginal and Torres Strait Islander peoples are advised that ANU Library collections may include images, names, voices, and other representations of deceased persons.

Material in the collection may contain terms, language or views that reflect the period in which the item was created and may be considered inappropriate today.

Pyrazolyl- N -heterocyclic carbene complexes of rhodium as hydrogenation catalysts: The influence of ligand steric bulk on catalyst activity

Date

Authors

Page, Michael

Wagler, Jorg

Messerle, Barbara Ann

Publisher

Royal Society of Chemistry

Abstract

A series of bidentate 1-(1-pyrazolylmethyl)-substituted NHC ligands (13a-c, 14a-c and 15a-c) were synthesised with substituents of varying steric bulk incorporated adjacent to the donor atoms. These ligands were coordinated to rhodium(I) to give a series

Keywords

Keywords: Catalytic activity; Complex structure; Donor atoms; Hydrogenation catalyst; Metal bounds; N-heterocyclic carbene complex; NHC ligands; Pyrazolyl; Single crystal x-ray diffraction; Solid-state structures; Steric bulk; Catalysis; Catalyst activity; Hydrogen

URI

http://hdl.handle.net/1885/57427

Collections

ANU Research Publications

Source

Dalton Transactions

Type

Journal article

DOI

10.1039/b906724h

Restricted until

2037-12-31

Downloads

File

Description

01_Page_Pyrazolyl-_N_-heterocyclic_2009.pdf (481.63 KB)