Dihydroperimidine-derived PNP pincer complexes as intermediates en route to N-heterocyclic carbene pincer complexes
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Hill, Anthony
McQueen, Caitlin
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American Chemical Society
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The reaction of N,N′-bis(dicyclohexylphosphinomethyl) dihydroperimidine (H2C(NCH2PCy2) 2C10H6-1,8, 1a) with [RuCl2(PPh 3)3] in THF affords the perimidinylidene-based N-heterocyclic carbene (per-NHC) pincer complex [RuCl2(OC 4H8){=C(NCH2PCy2)2C 10H6}] (2
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2037-12-31
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