Mixed-Metal Cluster Chemistry. 28. Core Enlargement of Tungsten-Iridium Clusters with Alkynyl, Ethyndiyl, and Butadiyndiyl Reagents

Date

2005

Authors

Dalton, Gulliver
Viau, Lydie
Waterman, Susan
Bruce, Michael
Low, Paul J
Roberts, Rachel
Willis, Anthony
Koutsantonis, George
Skelton, Brian
White, Allan

Journal Title

Journal ISSN

Volume Title

Publisher

American Chemical Society

Abstract

Reaction of [Wlr3(μ-CO)3(CO)8(η- C5Me5)] (1c) with [W(C=CPh)(CO)3(η-C5H5)] afforded the edge-bridged tetrahedral cluster [W2lr 3(μ4-η2-C2Ph)(μ-CO)(CO) 9(η-C5H5)(η-C5Me 5)] (3) and the edge-bridged trigonal-bipyramidal cluster [W 3lr3(μ4-η2-C 2Ph

Description

Keywords

Citation

Source

Inorganic Chemistry

Type

Journal article

Book Title

Entity type

Access Statement

License Rights

DOI

10.1021/ic050040+

Restricted until

2037-12-31