An organometallic tetranuclear complex of μ 4 -PO 4 : [{(Cp*Cr) 2 (μ-OMe) 2 } 2 (μ 4 -PO 4 )]X (X = I, PF 6 )

Shin, Richard; Tan, Geok Kheng; Koh, Lip; Goh, Lai Yoong; Webster, Richard

An organometallic tetranuclear complex of μ 4 -PO 4 : [{(Cp*Cr) 2 (μ-OMe) 2 } 2 (μ 4 -PO 4 )]X (X = I, PF 6 )

Date

2005

Authors

Shin, Richard

Tan, Geok Kheng

Koh, Lip

Goh, Lai Yoong

Webster, Richard

Publisher

American Chemical Society

Abstract

The first discrete organometallic tetranuclear μ4-PO 4 complex, [{(Cp*Cr)2(μ-OMe)2} 2(μ4-PO4)]+ (5; Cp* = η5-C5Me5), was isolated as the iodide and PF6 salts from the reaction between NaH2PO4 and [Cp*Cr(μ-OMe)I]2 (2), which was derived from thiolate