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Cross-dimerisation between different cisoid- and transoid-1,3-dienes at a ruthenium(0) centre

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Date

2013

Authors

Hirano, Masafumi
Inoue, Haruka
Okamoto, Takuya
Ueda, Takao
Komine, Nobuyuki
Komiya, Sanshiro
Wang, Xian-qi
Bennett, Martin

Journal Title

Journal ISSN

Volume Title

Publisher

Royal Society of Chemistry

Abstract

Reaction of [Ru(η4-cisoid-2,3-dimethyl-1,3-butadiene) (η4-1,5-COD)(NCMe)] with 1,3-butadiene gives the chelate bis(allylic)ruthenium(ii) complex supine,prone-[Ru(η3: η3-2,3-dimethylocta-2,6-diene-1,8-diyl)(η4-1, 5-COD)] (supine,prone-2da) in 75% isol

Description

Keywords

Keywords: 1,3 butadiene; alkadiene; chelate; cisoid 1,3 diene; ruthenium; transoid 1,3 diene; unclassified drug; article; dimerization; oxidative coupling; priority journal; X ray crystallography

Citation

URI

http://hdl.handle.net/1885/62510

Collections

ANU Research Publications

Source

New Journal of Chemistry

Type

Journal article

Book Title

Entity type

Access Statement

License Rights

DOI

10.1039/c3nj00429e

Restricted until

2037-12-31

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Description
01_Hirano_Cross-dimerisation_between_2013.pdf (1.87 MB)

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